Although it maybe slight, Heads cc will change everythime they are skimmed, so for talk sake you go and do your rebuild and allow the standard new head cc, your heads may well have been skimmed once or twice before etc etc so you dont know what cc you have untill you skim your heads and get them cc'd. Then you have to take into acount the pistons spec.. Different thickness head gaskets are available to correct and make the comp ratio you want. Also Resurfacing the block will have same effect as skimming head, more you take off the more you will raise the comp ratio.
Most guys can give you a rough idea of what you will end up with from there past experience, but only true accurate way is to measure everything and do the maths